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71.
A thermodynamically consistent extension of the constitutive equations of saturated soils to unsaturated conditions is often worked out through the use of a unique ‘effective’ interstitial pressure, accounting equivalently for the pressures of the saturating fluids acting separately on the internal solid walls of the pore network. The natural candidate for this effective interstitial pressure is the space averaged interstitial pressure. In contrast experimental observations have revealed that, at least, a pair of stress state variables was needed for a suitable framework to describe stress–strain–strength behaviour of unsaturated soils. The thermodynamics analysis presented here shows that the most general approach to the behaviour of unsaturated soils actually requires three stress state variables: the suction, which is required to describe the invasion of the soil by the liquid water phase through the retention curve; two effective stresses, which are required to describe the soil deformation at water saturation held constant. However a simple assumption related to the plastic flow rule leads to the final need of only a Bishop-like effective stress to formulate the stress–strain constitutive equation describing the soil deformation, while the retention properties still involve the suction and possibly the deformation. Commonly accepted models for unsaturated soils, that is the Barcelona Basic Model and any approach based on the use of an effective averaged interstitial pressure, appear as special extreme cases of the thermodynamic formulation proposed here.  相似文献   
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73.
In the framework of the management of karstic aquifers, geophysical reconnaissance can be used to locate conduits and caves, and to characterise the surrounding limestone matrix. Suitable characterisation of heterogeneities in the karstic environment is, however, challenging for ground-based geophysical methods. The present article describes the results, and evaluates the response and accuracy of combined geophysical measurements carried out at the Poumeyssen test site in France, involving electrical resistivity imaging (ERI), magnetic resonance sounding (MRS), “mise-à-la-masse” electrical mapping, and seismic tomography. This site provides the opportunity to study a relatively wide, shallow, water-filled conduit whose location and shape are known from topographic work carried out by cave divers. Seismic and MRS provided the exact location and width of the conduit, to within a few meters. The seismic and electrical data suggest that the limestone medium surrounding the conduit is not homogeneous.  相似文献   
74.
Powdered samples of carbon-nitrogen-hydrogen “tholins” that mimic Titan's atmosphere aerosols were produced under levitation conditions in the laboratory with a dusty plasma (PAMPRE experiment) using different initial N2:CH4 gas mixtures and studied using UV Raman and infrared spectroscopy, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). Comparison between the tholins produced in the PAMPRE experiments and samples prepared by other techniques reveal that they form a fairly homogeneous family of hydrogenated carbon nitride materials. Wall effects during the PAMPRE deposition experiments and other were found to have little effect on the chemical structure of tholins. The first-order UV Raman bands of the disordered carbonaceous materials point to a large contribution of sp2 clusters present compared with olefinic CN or CC groupings, whereas features at 690 and 980 cm−1 suggest C3N3 rings are present as a species inserted in the macromolecular network. Diffraction techniques do not indicate the presence of large polyaromatic species in any of the tholins studied, whatever their nitrogen concentration, in disagreement with certain previous observations. This precludes the idea that the nature and degree of absorption in the visible range is controlled by the size of polyaromatic species, as has been observed in series of carbon-based materials obtained via thermal processing. Infrared spectroscopy analysis of the tholins has confirmed earlier identifications of chemical groups present including primary amines, nitriles, and alkyl moieties such as CH2/CH3, but has ruled out CH2/CH3 branches appearing on secondary or tertiary amines. Similar analyses were also performed on a polymeric (HCN)x material, which was found to present several similarities with the tholins, hence suggesting similar polymerization processes.  相似文献   
75.
A method to estimate aquifer thickness and hydraulic conductivity has been developed, consisting of multiple pumping tests. The method requires short-duration pumping cycles on an unconfined aquifer with significant seasonal water-table fluctuations. The interpretation of several pumping tests at a site in India under various initial conditions provides information on the change in hydrodynamic parameters in relation to the initial water-table level. The transmissivity linearly decreases compared with the initial water level, suggesting a homogeneous distribution of hydraulic conductivity with depth. The hydraulic conductivity is estimated from the slope of this linear relationship. The extrapolation of the relationship between transmissivity and water level provides an estimate of the aquifer thickness that is in good agreement with geophysical investigations. The hydraulically active part of the aquifer is located in both the shallow weathered and the underlying densely fractured zones of the crystalline basement. However, no significant relationship is found between the aquifer storage coefficient and initial water level. This new method contributes to filling the methodological gap between single pumping tests and hydraulic tomography, in providing information on the variation of the global transmissivity according to depth. It can be applied to any unconfined aquifer experiencing large seasonal water-table fluctuations and short pumping cycles.  相似文献   
76.
This article describes the formation of the principal French high-purity silica placer (source for electrometallurgy of silicon and ferrosilicon), the Boudeau deposit in Dordogne, and of one of its subordinate deposits, the Pays Brûlé deposit. Boudeau has always been considered to be a colluvial deposit, formed in a trap produced by extensional tectonism. The present work suggests a new genetic interpretation, based on a combined study of the deposits and their underlying rocks. It shows that the quartz gravel deposits, laid down by stream flow within braided channels, were reworked by karstic progressive sinking, and that the mechanism responsible for the increase in the thickness of the economic formations is cryptokarstic corrosion. This undercovers weathering process, which involves dissolution of karstifiable rocks (oolitic and bioclastic limestones) at their interface with a permeable, non-karstifiable cover composed of chemically pure quartz gravels in a sandy-argillaceous matrix. A typological study of the gravels provides a basis for tackling the problem of their origin and their purity. They seem to be derived mainly from the synmetamorphic quartz mobilisates of the stripped metamorphic units (the lower and upper gneiss units forming the western edge of the Massif Central). Lastly, a dynamic model is suggested for the genesis of the high-purity silica deposits of Dordogne.  相似文献   
77.
78.
Flood frequency analysis is usually based on the fitting of an extreme value distribution to the local streamflow series. However, when the local data series is short, frequency analysis results become unreliable. Regional frequency analysis is a convenient way to reduce the estimation uncertainty. In this work, we propose a regional Bayesian model for short record length sites. This model is less restrictive than the index flood model while preserving the formalism of “homogeneous regions”. The performance of the proposed model is assessed on a set of gauging stations in France. The accuracy of quantile estimates as a function of the degree of homogeneity of the pooling group is also analysed. The results indicate that the regional Bayesian model outperforms the index flood model and local estimators. Furthermore, it seems that working with relatively large and homogeneous regions may lead to more accurate results than working with smaller and highly homogeneous regions.  相似文献   
79.
In order to investigate the microclimatic conditions in a street canyon, a physical model was used to conduct the Joint ATREUS-PICADA Experiment (JAPEX) in situ experimental campaign. Four lines of buildings simulated by steel containers were installed to form three parallel street canyons at 1:5 scale, with width/height aspect ratio approximately 0.40. The reference wind and atmospheric conditions were measured, as well as the flow velocity and direction in the street. Preliminary results concern street canyon ventilation and thermal effects on in-canyon airflow, and show that vortical motions appear for reference wind directions perpendicular to the street axis. The presence of adjacent rows of buildings did not appear to significantly influence the flow character within the canyon for the case of a low aspect ratio corresponding to a skimming flow regime. The flow structure was not significantly affected by the thermal effects although some slight interference occurred in the lower part of the canyon. An analysis of horizontal temperature gradients indicated that a thin boundary layer develops near the heated facade. These facts imply that the thermal effects are considerable only very close to the wall.  相似文献   
80.
The introduced green alga Caulerpa racemosa var. cylindracea has been rapidly spreading in the Mediterranean Sea since 1990. It was first observed in France in 1997 (Marseilles). In early 2004, the stretch of the French Mediterranean coastline and the surface area affected by the invasion were estimated at about 83 km and 4014 ha, respectively. The depth range of colonized areas was usually 10-35 m depth. Shallow (0-10 m) and deep (down to 40 m) dense meadows were rarely observed. In contrast to the dead matte of Posidonia oceanica, which constituted the most widely colonized substratum, dense P. oceanica meadows and fine sand with large ripple-marks were not invaded. Few rocky areas were colonized and coarse sand bottoms were usually colonized below 20 m depth. All the colonized areas were exposed to human activities and more than 40% were fishing areas. Mild climate, suitable substrata, presence of vectors of dispersal and absence of efficient biological control make the French Mediterranean coast particularly vulnerable to the further spread of the alga.  相似文献   
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